1-Methylnaphthalene → HCID 86673228, compound

HRID 1428441Notes

Reaction equation

HRID 1428441 reaction equation
[CH3:1][C:2]1[C:11]2[C:6](=[CH:7][CH:8]=[CH:9][CH:10]=2)[CH:5]=[CH:4][CH:3]=1.[C:12](Cl)(=[O:16])[C:13]([CH3:15])=[CH2:14].[Cl-].[Al+3].[Cl-].[Cl-]>ClCCl>[CH3:1][C:2]1[C:11]2[C:6](=[CH:7][C:8]([C:12](=[O:16])[C:13]([CH3:15])=[CH2:14])=[CH:9][CH:10]=2)[CH:5]=[CH:4][CH:3]=1

Participants

5

Reactant 3

HCID 70021-MethylnaphthaleneHCID 13528Methacryloyl chlorideHCID 6451240Aluminum(III) Chloride

Product 1

HCID 86673228HCID 86673228, compoundYield 58.1%

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

1-methylnaphthalene (142 mg), methacryloyl chloride (110 mg), and aluminium chloride (160 mg) were reacted in dichloromethane (1.5 mL) at from −30° C. to room temperature for 4 hours. The resultant was treated in the same manner as described in Example 1 to obtain the title compound (122 mg).

Workup

  1. additionThe resultant was treated in the same manner

Sources & evidence

ORD record
ord-1c887ca10d8a463fb28cd1f5ba0676b9
Source dataset
uspto-grants-2015_01
Patent number
US08937091B2

Reaction notes

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