1-Methylnaphthalene → HCID 86673229, compound

HRID 1428442Notes

Reaction equation

HRID 1428442 reaction equation
[CH3:1][C:2]1[C:11]2[C:6](=[CH:7][CH:8]=[CH:9][CH:10]=2)[CH:5]=[CH:4][CH:3]=1.[C:12](Cl)(=[O:15])[CH:13]=[CH2:14].[Cl-].[Al+3].[Cl-].[Cl-]>C(=S)=S>[CH3:1][C:2]1[C:11]2[C:6](=[CH:7][C:8]([C:12](=[O:15])[CH:13]=[CH2:14])=[CH:9][CH:10]=2)[CH:5]=[CH:4][CH:3]=1

Participants

5

Reactant 3

HCID 70021-MethylnaphthaleneHCID 13140Acryloyl chlorideHCID 6451240Aluminum(III) Chloride

Product 1

HCID 86673229HCID 86673229, compoundYield 86.2%

Reagents, catalysts & solvents 1

HCID 6348Carbon DisulfideSolvent

Procedure

1-methylnaphthalene (142 mg), acryloyl chloride (100 mg), and aluminium chloride (150 mg) were reacted in carbon disulfide (0.5 mL) at from −20° C. to room temperature for 1 hour. The resultant was treated in the same manner as described in Example 1 to obtain the title compound (169 mg) in a viscous liquid form.

Workup

  1. additionThe resultant was treated in the same manner

Sources & evidence

ORD record
ord-1c0ca1fbcf0d427baee0ec4b9f6b74dc
Source dataset
uspto-grants-2015_01
Patent number
US08937091B2

Reaction notes

Loading…