O-Xylene → HCID 57287622, compound

HRID 1428455Notes

Reaction equation

HRID 1428455 reaction equation
[C:1]1([CH3:8])[C:2]([CH3:7])=[CH:3][CH:4]=[CH:5][CH:6]=1.[C:9](Cl)(=[O:12])[CH:10]=[CH2:11].[Cl-].[Al+3].[Cl-].[Cl-]>ClCCl>[CH3:8][C:1]1[CH:6]=[C:5]([C:9](=[O:12])[CH:10]=[CH2:11])[CH:4]=[CH:3][C:2]=1[CH3:7]

Participants

5

Reactant 3

HCID 7237O-XyleneHCID 13140Acryloyl chlorideHCID 6451240Aluminum(III) Chloride

Product 1

HCID 57287622HCID 57287622, compound

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

Orthoxylene (0.5 mL), acryloyl chloride (120 mg), and aluminium chloride (150 mg) were reacted in dichloromethane (1.5 mL) at from 0° C. to room temperature for 4 hours. The resultant was treated in the same manner as described in Example 1 to obtain the title compound (160 mg).

Workup

  1. additionThe resultant was treated in the same manner

Sources & evidence

ORD record
ord-682eae5fdd2a4ae1a2cdbdf9875d736f
Source dataset
uspto-grants-2015_01
Patent number
US08937091B2

Reaction notes

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