Diphenylmethane → HCID 46913486, compound

HRID 1428463Notes

Reaction equation

HRID 1428463 reaction equation
[C:1]1([CH2:7][C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[C:14](Cl)(=[O:17])[CH:15]=[CH2:16].[Cl-].[Al+3].[Cl-].[Cl-]>ClCCl>[C:14]([CH:7]([C:8]1[CH:9]=[CH:10][CH:11]=[CH:12][CH:13]=1)[C:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1)(=[O:17])[CH:15]=[CH2:16]

Participants

5

Reactant 3

HCID 7580DiphenylmethaneHCID 13140Acryloyl chlorideHCID 6451240Aluminum(III) Chloride

Product 1

HCID 46913486HCID 46913486, compoundYield 85.6%

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

Diphenylmethane (168 mg), acryloyl chloride (200 mg), and aluminium chloride (280 mg) were reacted in dichloromethane (2 mL) at from −40° C. to room temperature for 2 hours. The resultant was treated in the same manner as described in Example 1 to obtain the title compound (190 mg).

Workup

  1. additionThe resultant was treated in the same manner

Sources & evidence

ORD record
ord-85a228579cfd4dad84214957fe3a8b61
Source dataset
uspto-grants-2015_01
Patent number
US08937091B2

Reaction notes

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