Iron → HCID 131732363, compound

HRID 1428698Notes

Reaction equation

HRID 1428698 reaction equation
[Fe:1].CCCCC(C([O-])=O)CC.CCCCC(C([O-])=O)CC.CCCCC(C([O-])=O)CC.[Fe+3].[CH2:33]([OH:119])[C@H:34]1[O:39][C@@H:38]2[O:40][C@H:41]3[C@H:46]([OH:47])[C@@H:45]([OH:48])[C@@H:44]([O:49][C@H:50]4[C@H:55]([OH:56])[C@@H:54]([OH:57])[C@@H:53]([O:58][C@H:59]5[C@H:64]([OH:65])[C@@H:63]([OH:66])[CH:62]([O:67][CH:68]6[C@H:73]([OH:74])[C@@H:72]([OH:75])[CH:71]([CH:76]7[C@H:81]([OH:82])[C@@H:80]([OH:83])[CH:79]([O:84][C@H:85]8[C@H:90]([OH:91])[C@@H:89]([OH:92])[C@@H:88]([O:93][C@H:94]9[C@H:100]([OH:101])[C@@H:99]([OH:102])[C@@H:97]([O:98][C@H:35]1[C@H:36]([OH:118])[C@H:37]2[OH:117])[O:96][C@@H:95]9[CH2:103][OH:104])[O:87][C@@H:86]8[CH2:105][OH:106])[O:78][C@@H:77]7[CH2:107][OH:108])[O:70][C@@H:69]6[CH2:109][OH:110])[O:61][C@@H:60]5[CH2:111][OH:112])[O:52][C@@H:51]4[CH2:113][OH:114])[O:43][C@@H:42]3[CH2:115][OH:116]>>[CH2:33]([OH:119])[C@H:34]1[O:39][C@@H:38]2[O:40][C@H:41]3[C@H:46]([OH:47])[C@@H:45]([OH:48])[C@@H:44]([O:49][C@H:50]4[C@H:55]([OH:56])[C@@H:54]([OH:57])[C@@H:53]([O:58][C@H:59]5[C@H:64]([OH:65])[C@@H:63]([OH:66])[CH:62]([O:67][CH:68]6[C@H:73]([OH:74])[C@@H:72]([OH:75])[CH:71]([CH:76]7[C@H:81]([OH:82])[C@@H:80]([OH:83])[CH:79]([O:84][C@H:85]8[C@H:90]([OH:91])[C@@H:89]([OH:92])[C@@H:88]([O:93][C@H:94]9[C@H:100]([OH:101])[C@@H:99]([OH:102])[C@@H:97]([O:98][C@H:35]1[C@H:36]([OH:118])[C@H:37]2[OH:117])[O:96][C@@H:95]9[CH2:103][OH:104])[O:87][C@@H:86]8[CH2:105][OH:106])[O:78][C@@H:77]7[CH2:107][OH:108])[O:70][C@@H:69]6[CH2:109][OH:110])[O:61][C@@H:60]5[CH2:111][OH:112])[O:52][C@@H:51]4[CH2:113][OH:114])[O:43][C@@H:42]3[CH2:115][OH:116].[Fe:1]

Participants

4

Reactant 3

HCID 23925IronHCID 110963Hexanoic acid, 2-ethyl-, iron(3+) salt (3:1)HCID 44431027gamma-Cyclodextrine

Product 1

HCID 131732363HCID 131732363, compound

Procedure

23 g of a iron organic salt, iron octoate 11% solution (OM Group, Inc.) was added to the above-noted γ-cylodextrin solution. A dark reddish brown precipitate formed upon addition of the drier. The mixture was stirred for at least 16 hours. The precipitate was filtered off under reduced pressure. The precipitate was dried under reduced pressure (around 19 InHg) at 50-60° C. The FTIR spectrum of the resultant inclusion complex is provided in FIG. 1(f).

Workup

  1. customA dark reddish brown precipitate formed upon addition of the drier
  2. filtrationThe precipitate was filtered off under reduced pressure
  3. dry with materialThe precipitate was dried under reduced pressure (around 19 InHg) at 50-60° C
  4. customThe FTIR spectrum of the resultant inclusion complex is provided in FIG. 1(f)

Sources & evidence

ORD record
ord-ca2a5dcffef74fd9b0f9586202002e5f
Source dataset
uspto-grants-2015_01
Patent number
US08937119B2

Reaction notes

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