HuagongsheHuagongshe Chemistry Print Report · For research reference only
HCID 68590505, compound → HCID 68590782, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | HCID 68590505 | HCID 68590505 | — |
| Catalyst | (1,3-Bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene)(dichloro)((2-((propan-2-yl)oxy)phenyl)methylidene)ruthenium | HCID 11763533 | — |
| Solvent | 1,2-Dichloroethane | HCID 11 | — |
| Product | HCID 68590782 | HCID 68590782 | 62% |
Reaction Steps
The diolefin 16d (0.95 g, 1.53 mmol) was reacted with Hoveyda Grubbs 2nd generation catalyst (140 mg) in DCE (900 ml) according to the procedure described in Example 13 step d which gave the crude title compound, (560 mg, 62%), (M+H)+565.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08937080B2 |
| Source dataset | uspto-grants-2015_01 |
| ORD ID | ord-e2341ad9af954a8fa1610980d026cd72 |
| Source note | uspto-grants-2015_01 |