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HRID1434920

反应详情

EQUATION

反应方程式

HRID 1434920 的结构方程式

REACTANTS

反应物

2
结构：CC1(C)CC(N)CC(C)(C)N1
HCID37524

2,2,6,6-Tetramethylpiperidin-4-amine

C9H20N2

结构：CS(=O)c1nccc(-c2ccc(Br)s2)n1
HCID57936157

未命名化合物

PRODUCTS

生成物

1
结构：CC1(C)CC(Nc2nccc(-c3ccc(Br)s3)n2)CC(C)(C)N1
HCID57936128

未命名化合物

PROCEDURE

实验过程

4-(5-Bromo-thiophen-2-yl)-2-methanesulfinyl-pyrimidine (110 mg, 0.36 mmol) and 4-amino-2,2,6,6,-tetramethyl piperidine (0.6 ml) were heated to 130° C. for 45 minutes. Evaporation and chromatography on silicagel (TBDME/MeOH/ammonia:90/9/1) gave the title compound as slightly coloured crystals. Yield: 100 mg (70%).

WORKUP

后处理

  1. customEvaporation and chromatography on silicagel (TBDME/MeOH/ammonia:90/9/1)