HRID14370

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID8920

Dihexylamine

C12H27N

结构：CCCN(CCC)c1ccc2nc3ccccc3[s+]c2c1.CCCN(CCC)c1ccc2nc3ccccc3[s+]c2c1.CCCN(CCC)c1ccc2nc3ccccc3[s+]c2c1.[I-].[I-].[I-]

HCID178457153

未命名化合物

PRODUCTS

生成物

结构：CCCCCCN(CCCCCC)c1ccc2nc3ccc(N(CCC)CCC)cc3[s+]c2c1.[I-]

HCID178444779

未命名化合物

PROCEDURE

实验过程

This compound was obtained following isolation of 3-(N,N-dipropylamino)-phenothiazin-5-ium triiodide and subsequent treatment with dihexylamine. Precipitation from dichloromethane by addition of diethyl ether yielded purple lustrous crystals. Mass spectrometry: C30H46N3OS requires m/z=480; found m/z=480 (I− not detected by mass spectrometry).

WORKUP

后处理

customThis compound was obtained
customPrecipitation from dichloromethane
additionby addition of diethyl ether yielded purple lustrous crystals

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-c49e6cb075be4fa28b8e94631fa0ee38
来源数据集: uspto-grants-2010_06
DOI: 10.6084/m9.figshare.5104873.v1
专利: US07732439B2
来源说明: uspto-grants-2010_06

反应 SMILES

[I-:1].[I-].[I-].[CH2:4]([N:7]([C:11]1[CH:12]=[CH:13][C:14]2[C:23]([CH:24]=1)=[S+:22][C:21]1[C:16](=[CH:17][CH:18]=[CH:19][CH:20]=1)[N:15]=2)[CH2:8][CH2:9][CH3:10])[CH2:5][CH3:6].C(N([C:32]1[CH:33]=[CH:34][C:35]2[C:44]([CH:45]=1)=[S+][C:42]1[C:37](=[CH:38][CH:39]=[CH:40][CH:41]=1)[N:36]=2)CCC)CC.C(N(C1C=CC2C(C=1)=[S+]C1C(=CC=CC=1)N=2)CCC)CC.C(NCCCCCC)CCCCC>>[I-:1].[CH2:37]([N:36]([C:19]1[CH:18]=[CH:17][C:16]2[C:21]([CH:20]=1)=[S+:22][C:23]1[C:14](=[CH:13][CH:12]=[C:11]([N:7]([CH2:8][CH2:9][CH3:10])[CH2:4][CH2:5][CH3:6])[CH:24]=1)[N:15]=2)[CH2:35][CH2:34][CH2:33][CH2:32][CH2:45][CH3:44])[CH2:38][CH2:39][CH2:40][CH2:41][CH3:42]