Potassium Cation → 3-Methyl-7-p-toluenesulfonyl-3,7-diazabicyclo[3.3.0]oct-1(5)-ene

HRID 143915Notes

Reaction equation

HRID 143915 reaction equation
[C:22](=[O:23])([O-:24])[O-:25].[CH3:20][NH2:21].[CH3:28][C:29]#[N:30].[K+:26].[K+:27].[c:1]1([CH3:19])[cH:2][cH:3][c:4]([S:7](=[O:8])(=[O:9])[N:10]2[CH2:11][C:12]([CH2:17][Br:18])=[C:13]([CH2:15][Br:16])[CH2:14]2)[cH:5][cH:6]1>>[c:1]1([CH3:19])[cH:2][cH:3][c:4]([S:7](=[O:8])(=[O:9])[N:10]2[CH2:11][C:12]3=[C:13]([CH2:14]2)[CH2:15][N:21]([CH3:20])[CH2:17]3)[cH:5][cH:6]1

Participants

6

Reactant 5

HCID 813Potassium Cation2×HCID 6329MethylamineHCID 6342AcetonitrileHCID 19660Carbonate IonHCID 199082361-p-Toluenesulfonyl-3,4-bis(bromomethyl)-3-pyrroline

Product 1

HCID 199100673-Methyl-7-p-toluenesulfonyl-3,7-diazabicyclo[3.3.0]oct-1(5)-ene

Sources & evidence

ORD record
ord-841f20d4a30f4062b12fae32b34542b8
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (9/10)

Reaction notes

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