Dichloromethane → N-Methyl-N-(2-methyl-1,3-dichloro-2-propanesulfenyl)carbamoyl fluoride

HRID 1439197Notes

Reaction equation

HRID 1439197 reaction equation
[CH2:1]([Cl:5])[C:2](=[CH2:4])[CH3:3].[CH3:6][N:7]([S:11]Cl)[C:8]([F:10])=[O:9].C(Cl)[Cl:14]>>[CH3:6][N:7]([S:11][C:2]([CH3:3])([CH2:4][Cl:14])[CH2:1][Cl:5])[C:8]([F:10])=[O:9]

Participants

4

Reactant 3

HCID 6344DichloromethaneHCID 112413-Chloro-2-methyl-1-propeneHCID 12922862N-chlorothio(methyl)carbamoyl fluoride

Product 1

HCID 54204012N-Methyl-N-(2-methyl-1,3-dichloro-2-propanesulfenyl)carbamoyl fluoride

Procedure

To a solution of 1.35g of methallyl chloride in 25 ml of methylene chloride was added 2.15g of N-methyl-N-chlorosulfenyl carbamoyl fluoride. The solution was heated to reflux for 45 min. and concentrated to 1.68g of pale yellow oil.

Workup

  1. temperatureThe solution was heated
  2. temperatureto reflux for 45 min.
  3. concentrationconcentrated to 1.68g of pale yellow oil

Sources & evidence

ORD record
ord-d9e055816b2943b28be3fc34bc7e884f
Source dataset
uspto-grants-1977_11
Patent number
US04058549

Reaction notes

Loading…