Sodium → 1-[2-(Tetradecyloxy)phenyl]-1,3-butanedione

HRID 1439348Notes

Reaction equation

HRID 1439348 reaction equation
CO[C:3](=[O:25])[C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][C:5]=1[O:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH3:24].[Na]>CC(C)=O>[O:25]=[C:3]([C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][C:5]=1[O:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH3:24])[CH2:4][C:5](=[O:10])[CH3:6]

Participants

4

Reactant 2

HCID 5360545SodiumHCID 12361482HCID 12361482, compound

Product 1

HCID 213968591-[2-(Tetradecyloxy)phenyl]-1,3-butanedione

Reagents, catalysts & solvents 1

HCID 180AcetoneSolvent

Procedure

1,3-dioxo-1(2-tetradecyloxyphenyl)-butane was prepared by reacting 2-tetradecyloxybenzoic acid methyl ester and acetone in the presence of sodium ions as described by Bloch and v.Konstanecki in Ber. 33, 1998.

Sources & evidence

ORD record
ord-851ad31dfb994d4b829836afa0c350ff
Source dataset
uspto-grants-1977_11
Patent number
US04059447

Reaction notes

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