Potassium Carbonate → HCID 20512687, compound

HRID 1439472Notes

Reaction equation

HRID 1439472 reaction equation
C(O)(=O)C(O)=O.[CH2:7]([S:15][CH:16]([CH2:24][CH2:25][CH2:26][CH2:27][CH3:28])[CH2:17][CH2:18][N:19]1[CH:23]=[CH:22][N:21]=[CH:20]1)[CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH3:14].C(=O)([O-])[O-].[K+].[K+]>ClCCl>[CH2:7]([S:15][CH:16]([CH2:24][CH2:25][CH2:26][CH2:27][CH3:28])[CH2:17][CH2:18][N:19]1[CH:23]=[CH:22][N:21]=[CH:20]1)[CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH3:14]

Participants

4

Reactant 2

HCID 11430Potassium CarbonateHCID 20512686HCID 20512686, compound

Product 1

HCID 20512687HCID 20512687, compound

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

1-(3-Octylthiooctyl)imidazole oxalate (2.0 g.) in 100 ml. of dichloromethane was shaken with excess dilute potassium carbonate solution until the salt was completely dissolved. The organic layer was then separated, washed twice with water, dried over magnesium sulfate and evaporated to yield 1-(3-octylthiooctyl)imidazole as an oil.

Workup

  1. dissolutionwas completely dissolved
  2. customThe organic layer was then separated
  3. washwashed twice with water
  4. dry with materialdried over magnesium sulfate
  5. customevaporated

Sources & evidence

ORD record
ord-7af8341763994f648787421f6cd5cc61
Source dataset
uspto-grants-1977_11
Patent number
US04059705

Reaction notes

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