Methylamine → HCID 13571229, compound

HRID 1440035Notes

Reaction equation

HRID 1440035 reaction equation
[CH:1]([CH:3]1[O:8][C:6](=O)[CH2:5][CH2:4]1)=[CH2:2].[CH3:9][NH2:10]>>[CH:1]([CH:3]1[N:10]([CH3:9])[C:6](=[O:8])[CH2:5][CH2:4]1)=[CH2:2]

Participants

3

Reactant 2

HCID 6329MethylamineHCID 10920473gamma-vinylbutyrolactone

Product 1

HCID 13571229HCID 13571229, compoundYield 46%

Procedure

21 g (179 mmol) of gamma-vinylbutyrolactone prepared as in Example 1 were stirred with 125 g of 40% strength aqueous methylamine in an autoclave at 280° C. for two hours. After cooling, the reaction mixture was concentrated at 50° C./20 mbar. The residue (22.7 g) was distilled using a spinning band column to yield 10.3 g (46%) of 5-vinyl-N-methylpyrrolidone.

Workup

  1. temperatureAfter cooling
  2. concentrationthe reaction mixture was concentrated at 50° C./20 mbar
  3. distillationThe residue (22.7 g) was distilled

Sources & evidence

ORD record
ord-8b612a6a888a4820bb99f2c4b2cb97b8
Source dataset
uspto-grants-1996_03
Patent number
US05496958

Reaction notes

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