2-Tert-Butylphenol → HCID 10935541, compound

HRID 1440369Notes

Reaction equation

HRID 1440369 reaction equation
[C:1]1([P:7](OCC)[O:8][CH2:9][CH3:10])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[C:14]([C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][C:19]=1[OH:24])([CH3:17])([CH3:16])[CH3:15]>>[C:1]1([P:7]([O:24][C:19]2[CH:20]=[CH:21][CH:22]=[CH:23][C:18]=2[C:14]([CH3:17])([CH3:15])[CH3:16])[O:8][CH2:9][CH3:10])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1

Participants

3

Reactant 2

HCID 69232-Tert-ButylphenolHCID 74225Diethyl phenylphosphonite

Product 1

HCID 10935541HCID 10935541, compound

Conditions

Temperature
180 °C

Procedure

99 g (0.5 mol) of diethyl phenylphosphonite and 75 g (0.5 mol) of 2-tert-butylphenol were mixed and heated with stirring at 530mbar to 170° C. Ethanol distilled off during this via a small column. The temperature was then increased stepwise to 180° C., and the vacuum was simultaneously enhanced to 100mbar. After 16 hours, a total of 18 g of ethanol distilled off. The batch was then cooled and distilled. After a first fraction, which contained the unreacted starting materials, 116 g were obtained having a boiling point of 139° C. at 0.1 mbar. The yield was thus for a 78% conversion rate almost 100% of theory.

Workup

  1. temperatureheated
  2. distillationEthanol distilled off during this via a small column
  3. distillationa total of 18 g of ethanol distilled off
  4. temperatureThe batch was then cooled
  5. distillationdistilled
  6. custom116 g were obtained

Sources & evidence

ORD record
ord-840dc774df3a48f1bbde6da54efe1cdb
Source dataset
uspto-grants-1996_03
Patent number
US05498741

Reaction notes

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