HuagongsheHuagongshe Chemistry Print Report · For research reference only
Hydroquinone → Lauryl acrylate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Hydroquinone | HCID 785 | — |
| Reactant | Methyl Acrylate | HCID 7294 | — |
| Reactant | 1-Dodecanol | HCID 8193 | — |
| Reactant | 4-Methoxyphenol | HCID 9015 | — |
| Reactant | Dimethyltin dichloride | HCID 12955 | — |
| Reactant | Tin atom | HCID 5352426 | — |
| Reactant | Sodium Methoxide | HCID 10942334 | — |
| Solvent | Heptane | HCID 8900 | — |
| Product | Lauryl acrylate | HCID 75084 | 93.2% |
Reaction Steps
In a similar manner, a mixture of 559 parts n-dodecyl alcohol, 387.4 parts methyl acrylate, 167 parts heptane, 1.5 parts dimethyltin dichloride, 0.4 parts sodium methoxide (molar ratio 1.08:1), 3.3 parts 4-methoxyphenol and 0.65 parts hydroquinone yielded, after work up, 672.2 parts (93.2 percent yield, based on n-dodecyl alcohol) of n-dodecyl acrylate, with a purity of 96.6 percent containing no detectable tin.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05498751 |
| Source dataset | uspto-grants-1996_03 |
| ORD ID | ord-29b7ab5d696e4680a351edbca0fdab9a |
| Source note | uspto-grants-1996_03 |