HCID 18982548, compound → HCID 18982489, compound

HRID 1440892Notes

Reaction equation

HRID 1440892 reaction equation
[CH2:1]([B-:5]([C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1)([C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1)[C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1)[CH2:2][CH2:3][CH3:4].[Li+].[Cl-].[CH3:26][S+:27]([CH3:36])[CH2:28][C:29]1[CH:34]=[CH:33][C:32]([Cl:35])=[CH:31][CH:30]=1>O>[CH3:26][S+:27]([CH3:36])[CH2:28][C:29]1[CH:34]=[CH:33][C:32]([Cl:35])=[CH:31][CH:30]=1.[CH2:1]([B-:5]([C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1)([C:6]1[CH:7]=[CH:8][CH:9]=[CH:10][CH:11]=1)[C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1)[CH2:2][CH2:3][CH3:4]

Participants

4

Reactant 2

HCID 18982548HCID 18982548, compoundHCID 23668465HCID 23668465, compound

Product 1

HCID 18982489HCID 18982489, compoundYield 93.1%

Reagents, catalysts & solvents 1

HCID 962WaterSolvent2×

Procedure

An aqueous solution of 11.27 g of lithium butyltriphenylborate in 200 ml of water was added to an aqueous solution of 8.21 g of dimethyl-p-chlorobenzylsulfonium chloride in 200 ml of water, and the resultant mixture was stirred at room temperature for 30 minutes. Then, the reaction mixture was filtered, and the resultant crystal was washed with water and dried to give 16.67 g of dimethyl-p-chlorobenzylsulfonium-butyltriphenylborate as a white crystal.

Workup

  1. filtrationThen, the reaction mixture was filtered
  2. washthe resultant crystal was washed with water
  3. customdried

Sources & evidence

ORD record
ord-d19b8ba586f840c1961acd4be2ceb9c7
Source dataset
uspto-grants-1996_03
Patent number
US05500453

Reaction notes

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