Water → HCID 88398096, compound

HRID 1440919Notes

Reaction equation

HRID 1440919 reaction equation
[C:1]([CH:5]=[CH:6][B-:7]([C:22]1[CH:27]=[CH:26][C:25]([Br:28])=[CH:24][CH:23]=1)([C:15]1[CH:20]=[CH:19][C:18]([Br:21])=[CH:17][CH:16]=1)[C:8]1[CH:13]=[CH:12][C:11]([Br:14])=[CH:10][CH:9]=1)([CH3:4])([CH3:3])[CH3:2].[Li+].F[Sb-](F)(F)(F)(F)F.[C:37]1([S+:43]([C:57]2[C:66]3[C:61](=[CH:62][CH:63]=[CH:64][CH:65]=3)[CH:60]=[CH:59][CH:58]=2)[CH2:44][C:45]([C:47]2[C:56]3[C:51](=[CH:52][CH:53]=[CH:54][CH:55]=3)[CH:50]=[CH:49][CH:48]=2)=[O:46])[CH:42]=[CH:41][CH:40]=[CH:39][CH:38]=1.O>C(#N)C>[C:37]1([S+:43]([C:57]2[C:66]3[C:61](=[CH:62][CH:63]=[CH:64][CH:65]=3)[CH:60]=[CH:59][CH:58]=2)[CH2:44][C:45]([C:47]2[C:56]3[C:51](=[CH:52][CH:53]=[CH:54][CH:55]=3)[CH:50]=[CH:49][CH:48]=2)=[O:46])[CH:38]=[CH:39][CH:40]=[CH:41][CH:42]=1.[C:1]([CH:5]=[CH:6][B-:7]([C:8]1[CH:13]=[CH:12][C:11]([Br:14])=[CH:10][CH:9]=1)([C:15]1[CH:20]=[CH:19][C:18]([Br:21])=[CH:17][CH:16]=1)[C:22]1[CH:23]=[CH:24][C:25]([Br:28])=[CH:26][CH:27]=1)([CH3:4])([CH3:2])[CH3:3]

Participants

5

Reactant 3

HCID 962WaterHCID 18982517HCID 18982517, compoundHCID 131719328HCID 131719328, compound

Product 1

HCID 88398096HCID 88398096, compound

Reagents, catalysts & solvents 1

HCID 6342AcetonitrileSolvent2×

Procedure

A solution of 5.58 g of lithium (2-tert-butylethenyl)tris(p-bromophenyl)borate in 50 ml of acetonitrile was added to a solution of 6.41 g of phenyl(1-naphthyl)(1-naphthyl-carbonylmethyl)sulfonium hexafluoroantimonate in 100 ml of acetonitrile, and the resultant mixture was stirred at room temperature for 30 minutes. Then, 200 ml of water was added. The resultant precipitate of a yellow oily component was recovered, and 100 ml of dichloromethane was added. The dichloromethane layer was washed with water, dried and concentrated to give 4.27 of phenyl(1-naphthyl)(1-naphthyl-carbonylmethyl)sulfonium-(2-tert-butylethenyl)tris(p-bromophenyl)borate.

Workup

  1. customThe resultant precipitate of a yellow oily component was recovered
  2. addition100 ml of dichloromethane was added
  3. washThe dichloromethane layer was washed with water
  4. customdried
  5. concentrationconcentrated

Sources & evidence

ORD record
ord-e25f3d92470341fc8ba35ab9fc96f1fd
Source dataset
uspto-grants-1996_03
Patent number
US05500453

Reaction notes

Loading…