Water → HCID 88398164, compound

HRID 1440920Notes

Reaction equation

HRID 1440920 reaction equation
[C:1]([CH:5]=[CH:6][B-:7]([C:26]1[C:31]([CH3:32])=[CH:30][C:29]([CH3:33])=[CH:28][C:27]=1[CH3:34])([C:17]1[C:22]([CH3:23])=[CH:21][C:20]([CH3:24])=[CH:19][C:18]=1[CH3:25])[C:8]1[C:13]([CH3:14])=[CH:12][C:11]([CH3:15])=[CH:10][C:9]=1[CH3:16])([CH3:4])([CH3:3])[CH3:2].[Na+].Cl([O-])(=O)(=O)=O.[C:41]1([S+:47]([C:58]2[CH:63]=[CH:62][CH:61]=[CH:60][CH:59]=2)[CH2:48][C:49]([C:51]2[CH:56]=[CH:55][C:54]([F:57])=[CH:53][CH:52]=2)=[O:50])[CH:46]=[CH:45][CH:44]=[CH:43][CH:42]=1.O>CC(C)=O.C(#N)C>[C:58]1([S+:47]([C:41]2[CH:46]=[CH:45][CH:44]=[CH:43][CH:42]=2)[CH2:48][C:49]([C:51]2[CH:52]=[CH:53][C:54]([F:57])=[CH:55][CH:56]=2)=[O:50])[CH:59]=[CH:60][CH:61]=[CH:62][CH:63]=1.[C:1]([CH:5]=[CH:6][B-:7]([C:8]1[C:13]([CH3:14])=[CH:12][C:11]([CH3:15])=[CH:10][C:9]=1[CH3:16])([C:26]1[C:31]([CH3:32])=[CH:30][C:29]([CH3:33])=[CH:28][C:27]=1[CH3:34])[C:17]1[C:22]([CH3:23])=[CH:21][C:20]([CH3:24])=[CH:19][C:18]=1[CH3:25])([CH3:4])([CH3:3])[CH3:2]

Participants

6

Reactant 3

HCID 962WaterHCID 18982526HCID 18982526, compoundHCID 131719329HCID 131719329, compound

Product 1

HCID 88398164HCID 88398164, compound

Reagents, catalysts & solvents 2

HCID 180AcetoneSolventHCID 6342AcetonitrileSolvent

Procedure

A solution of 5.59 g of sodium (2-tert-butylethenyl)trimesitylborate in 50 ml of acetone was added to a solution of 5.00 g of diphenyl-p-fluorophenacylsulfonium perchlorate in 100 ml of acetonitrile, and the resultant mixture was stirred at room temperature for 30 minutes. Then, 200 ml of water was added. The resultant precipitate of a yellow oily component was recovered, and 100 ml of dichloromethane was added. The dichloromethane layer was washed with water, dried and concentrated to give 3.11 of diphenyl-p-fluorophenacylsulfonium-(2-tert-butylethenyl)trimesitylborate.

Workup

  1. customThe resultant precipitate of a yellow oily component was recovered
  2. addition100 ml of dichloromethane was added
  3. washThe dichloromethane layer was washed with water
  4. customdried
  5. concentrationconcentrated

Sources & evidence

ORD record
ord-4ade70b12e84457da2bf2eb0d1e7e8bd
Source dataset
uspto-grants-1996_03
Patent number
US05500453

Reaction notes

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