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HRID1441191

反应详情

EQUATION

反应方程式

HRID 1441191 的结构方程式

REACTANTS

反应物

6
结构：O=C(O)CNC(=O)OCC1c2ccccc2-c2ccccc21
HCID93124

N-(9H-(fluoren-9-ylmethoxy)carbonyl)glycine

C17H15NO4

结构：O=C(N[C@@H](Cc1c[nH]c2ccccc12)C(=O)O)OCC1c2ccccc2-c2ccccc21
HCID978343

未命名化合物

结构：CN(C(=O)OCC1c2ccccc2-c2ccccc21)[C@@H](Cc1ccccc1)C(=O)O
HCID978356

未命名化合物

结构：CC[C@H](C)[C@H](NC(=O)OCC1c2ccccc2-c2ccccc21)C(=O)O
HCID2724629

N-Fmoc-L-isoleucine

C21H23NO4

结构：CCCC[C@H](NC(=O)OCC1c2ccccc2-c2ccccc21)C(=O)O
HCID7009636

Fmoc-L-norleucine

C21H23NO4

结构：CC(C)(C)OC(=O)C[C@@H](NC(=O)OCC1c2ccccc2-c2ccccc21)C(=O)O
HCID7018816

未命名化合物

PRODUCTS

生成物

4
结构：N[C@@H](Cc1ccccc1)C(=O)O
HCID6140

L-Phenylalanine

C9H11NO2

结构：N[C@@H](Cc1c[nH]c2ccccc12)C(=O)O
HCID6305

L-Tryptophan

C11H12N2O2

结构：CC[C@H](C)[C@H](N)C(=O)O
HCID6306

DL-Isoleucine

C6H13NO2

结构：CN[C@@H](Cc1ccccc1)C(=O)O
HCID6951135

N-Methyl-L-phenylalanine

C10H13NO2

PROCEDURE

实验过程

By following essentially the procedure of Table 2 and sequentially coupling Fmoc-MePhe-OH, Fmoc-DAsp(OtBu)-OH, Fmoc-Ile-OH, Fmoc-Trp-OH, Fmoc-Gly-OH, Fmoc-Ahx-OH and Hpa-OSu, the title compound was prepared. Amino Acid analysis following acid decomposition gave Asp 0.96 (1), Gly 1.04 (1), Ile 0.96 (1), MePhe 1.07 (1), Ahx 0.98 (1), Trp 0.61 (1), NH3 0.89. MS (FAB): m/e 895 (M-H)-.