1-Phenylcyclohexene → Cyclohexylbenzene

HRID 1444857Notes

Reaction equation

HRID 1444857 reaction equation
[H][H].[C:3]1([C:9]2[CH2:14][CH2:13][CH2:12][CH2:11][CH:10]=2)[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1>C1COCC1>[C:3]1([CH:9]2[CH2:14][CH2:13][CH2:12][CH2:11][CH2:10]2)[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1

Participants

4

Reactant 2

HCID 130431-Phenylcyclohexene2×HCID 178418361HCID 178418361, compound

Product 1

HCID 13229CyclohexylbenzeneYield 99%

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Procedure

In Example 7, hydrogenation reaction was conducted under the same condition as Example 1 for THF diluted solution concentration of the substance to be reduced, its flow rate, and hydrogen 9 flow rate, using 1-phenylcyclohexene as the substance to be reduced. The reaction time was within five minutes. The analytical result of the reaction product by 1H-NMR showed almost complete hydrogenation of 1-phenylcyclohexene, and phenylcyclohexane was obtained at 99% yield (See FIG. 6.).

Workup

  1. customIn Example 7, hydrogenation reaction
  2. customThe analytical result of the reaction product

Sources & evidence

ORD record
ord-209585531d684a89837168186c526993
Source dataset
uspto-grants-2010_02
Patent number
US07663008B2

Reaction notes

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