Hydrogen Peroxide → HCID 59169122, compound

HRID 1445293Notes

Reaction equation

HRID 1445293 reaction equation
[CH2:1]([O:4][CH2:5][CH2:6][C:7]([OH:9])=[O:8])[CH2:2]C.OO.S(=O)(=O)(O)[OH:13].[I-].[K+].S([O-])([O-])(=O)=S.[Na+].[Na+].C(OO)=O>>[CH2:1]([O:4][CH2:5][CH2:6][C:7]([O:9][OH:13])=[O:8])[CH3:2]

Participants

6

Reactant 5

HCID 784Hydrogen PeroxideHCID 1118Sulfuric AcidHCID 66051Performic AcidHCID 150334603-Propoxypropanoic acidHCID 21461527HCID 21461527, compound

Product 1

HCID 59169122HCID 59169122, compound

Procedure

3-Propoxypropionic acid (25.0 g, 189 mmol) was added with 50% aqueous hydrogen peroxide (16.4 mL, 284 mmol) and concentrated sulfuric acid (0.5 mL, 9.4 mmol) and left at room temperature for 4 days. Potassium iodide/sodium thiosulfate titration as described in Example 1 was conducted to determine the concentration of peroxycarboxylic acid 3 (Compound 3) after the 4 days.

Workup

  1. customafter the 4 days

Sources & evidence

ORD record
ord-934c9f21e8864217ba9789a1c01cb2bd
Source dataset
uspto-grants-2010_02
Patent number
US07666354B2

Reaction notes

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