Toluene → HCID 20550608, compound

HRID 1447324Notes

Reaction equation

HRID 1447324 reaction equation
[CH3:1][C:2]1[C:7]([NH2:8])=[C:6]([N+:9]([O-:11])=[O:10])[CH:5]=[C:4]([N+:12]([O-:14])=[O:13])[CH:3]=1.C1(C)C=CC=CC=1.ClS([N:26]=[C:27]=[O:28])(=O)=O.ClS(NC(N)=O)(=O)=O>O>[CH3:1][C:2]1[C:7]([NH:8][C:27]([NH2:26])=[O:28])=[C:6]([N+:9]([O-:11])=[O:10])[CH:5]=[C:4]([N+:12]([O-:14])=[O:13])[CH:3]=1

Participants

6

Reactant 4

HCID 1140TolueneHCID 70918Chlorosulfonyl isocyanateHCID 3453042-methyl-4,6-dinitroanilineHCID 22318895HCID 22318895, compound

Product 1

HCID 20550608HCID 20550608, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

40 of 6-methyl-2,4-dinitroaniline are stirred for 4 hours at 80° C. in 500 parts of toluene with 34 parts of chlorosulfonyl isocyanate. The suspension of the chlorosulfonyl urea obtained is mixed at 25° C. with 40 parts of water and saponified at 60° C. to give 6-methyl-2,4-dinitrophenyl urea.

Workup

  1. customobtained
  2. customsaponified at 60° C.

Sources & evidence

ORD record
ord-d44cbd0ccdae403dbcb1b2c68cd068ff
Source dataset
uspto-grants-1982_02
Patent number
US04316861

Reaction notes

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