2-Nitrophenol → HCID 20339191, compound

HRID 1447736Notes

Reaction equation

HRID 1447736 reaction equation
[N+:1]([C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][C:5]=1[OH:10])([O-:3])=[O:2].[CH2:11]([O:14][CH2:15]Br)[CH2:12][CH3:13].C(=O)([O-])[O-].[K+].[K+]>CC(C)=O>[CH2:11]([O:14][CH2:15][O:10][C:5]1[CH:6]=[CH:7][CH:8]=[CH:9][C:4]=1[N+:1]([O-:3])=[O:2])[CH2:12][CH3:13]

Participants

5

Reactant 3

HCID 69472-NitrophenolHCID 11430Potassium CarbonateHCID 14771605HCID 14771605, compound

Product 1

HCID 20339191HCID 20339191, compound

Reagents, catalysts & solvents 1

HCID 180AcetoneSolvent

Procedure

2-Nitrophenol, bromomethyl propyl ether, anhydrous potassium carbonate and acetone were reacted according to the procedure outlined in Example 1 to yield 2-propoxymethoxynitrobenzene, which was reduced to the corresponding aniline, and isolated by a vacuum distillation.

Sources & evidence

ORD record
ord-27ce91ad429145ccb90f3b67b4e348f3
Source dataset
uspto-grants-1979_12
Patent number
US04178168

Reaction notes

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