Trifluoroacetic acid → Trifluoroacetate
Reaction equation
C(OC([N:8]([N+:36]([O-:38])=[O:37])[C@H:9]([C:17]([CH:19]([NH2:35])[CH2:20][CH2:21][CH2:22][C@@H:23]([C:25]([N:27]1[CH2:34][CH2:33][CH2:32][C@H:28]1[C:29]([OH:31])=[O:30])=[O:26])[NH2:24])=[O:18])[CH2:10][CH2:11][CH2:12][NH:13][C:14](=[NH:16])[NH2:15])=O)(C)(C)C.[F:39][C:40]([F:45])([F:44])[C:41]([OH:43])=[O:42]>>[F:39][C:40]([F:45])([F:44])[C:41]([O-:43])=[O:42].[N+:36]([NH:8][C@H:9]([C:17]([CH:19]([NH2:35])[CH2:20][CH2:21][CH2:22][C@@H:23]([C:25]([N:27]1[CH2:34][CH2:33][CH2:32][C@H:28]1[C:29]([OH:31])=[O:30])=[O:26])[NH2:24])=[O:18])[CH2:10][CH2:11][CH2:12][NH:13][C:14](=[NH:15])[NH2:16])([O-:38])=[O:37]Participants
4
Procedure
the product of stage (d) is treated with trifluoroacetic acid to obtain trifluoroacetate of α-benzyloxycarbonyl, ε-(nitroarginyl) lysylproline;
Sources & evidence
- ORD record
- ord-e740301fa82042cc89f5126319014f48
- Source dataset
- uspto-grants-1980_02
- Patent number
- US04187217
Reaction notes
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