Chromic Acid → HCID 12734622, compound

HRID 1448747Notes

Reaction equation

HRID 1448747 reaction equation
[CH3:1][C@@H:2]1[CH2:7][CH2:6][CH2:5][CH2:4][C@H:3]1[CH:8]([OH:10])[CH3:9].[Cr](O)(O)(=O)=O>CCOCC>[CH3:9][C:8]([CH:3]1[CH2:4][CH2:5][CH2:6][CH2:7][CH:2]1[CH3:1])=[O:10]

Participants

4

Reactant 2

HCID 24425Chromic AcidHCID 53882190HCID 53882190, compound

Product 1

HCID 12734622HCID 12734622, compound

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent

Conditions

Temperature
10 °C

Procedure

A solution of 13.2 g. (0.0928 moles) cis/trans-1-(2-methylcyclohexyl)-1-ethanol in 50 ml. of ether was chilled in an ice bath and 50 ml. 2 N chromic acid solution (BROWN GARG-Reagent) was added dropwise, with stirring, at such a rate as to maintain the temperature at about 10° C. After the addition was complete, the ice bath was removed and the stirring was continued at ambient temperature for one hour.

Workup

  1. additionAfter the addition
  2. customthe ice bath was removed

Sources & evidence

ORD record
ord-2f6972e9508545dca6311ef789d0fcd5
Source dataset
uspto-grants-1980_02
Patent number
US04187251

Reaction notes

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