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HRID1449014

反应详情

EQUATION

反应方程式

HRID 1449014 的结构方程式

REACTANTS

反应物

3
结构：CSc1ccccc1C=O
HCID286443

2-(Methylthio)benzaldehyde

C8H8OS

结构：CCOC(=O)/C=C(/C)N
HCID643756

未命名化合物

结构：CCOC(=O)CC(=O)CN1C(=O)c2ccccc2C1=O
HCID701239

Ethyl 4-(1,3-dioxo-1,3-dihydro-2H-isoindol-2-yl)-3-oxobutanoate

C14H13NO5

PRODUCTS

生成物

1
结构：CCOC(=O)C1=C(C)NC(CN2C(=O)c3ccccc3C2=O)=C(C(=O)OCC)C1c1ccccc1SC
HCID70592102

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CCO
溶剂HCID702

Ethanol

C2H6O

PROCEDURE

实验过程

A solution of 10 g of 2-methylmercapto-benzaldehyde (77% pure), 14 g of phthalimidoacetoacetic acid ethyl ester and 6.5 g of β-aminocrotonic acid ethyl ester in 100 ccs of ethanol is heated under reflux for 2×24 hours and, after subsequent cooling, the precipitate is filtered off.

WORKUP

后处理

  1. temperatureunder reflux for 2×24 hours
  2. filtrationafter subsequent cooling, the precipitate is filtered off