Water → HCID 20349678, compound

HRID 1449417Notes

Reaction equation

HRID 1449417 reaction equation
C(O[C:4]1([C:14]([CH3:17])([CH3:16])[CH3:15])[C:8]([CH2:9][C:10]([CH3:13])([CH3:12])[CH3:11])=[CH:7][S:6][S:5]1)C.[Cl:18]([OH:22])(=[O:21])(=[O:20])=[O:19].O>C(O)C>[Cl:18]([O-:22])(=[O:21])(=[O:20])=[O:19].[CH2:9]([C:8]1[CH:7]=[S+:6][S:5][C:4]=1[C:14]([CH3:17])([CH3:16])[CH3:15])[C:10]([CH3:13])([CH3:12])[CH3:11]

Participants

5

Reactant 3

HCID 962WaterHCID 24247Perchloric AcidHCID 20349680HCID 20349680, compound

Product 1

HCID 20349678HCID 20349678, compoundYield 100.3%

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

A sample of 11.4 grams of 3ethoxy-3-t-butyl-4-neopentyl 1,2 dithiole dissolved in 15 grams of ethanol was treated with 14 grams of 70% perchloric acid. To the mixture was added 100 grams of water and the precipitate which formed was filtered off. There was isolated 13.7 grams (100% of theory) of 4-neopentyl-3-tertiarybutyl 1,2 dithiolium perchlorate.

Workup

  1. customthe precipitate which formed
  2. filtrationwas filtered off

Sources & evidence

ORD record
ord-4179bd76816946e28def8f1f34dcee90
Source dataset
uspto-grants-1980_02
Patent number
US04190727

Reaction notes

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