Sodium Azide → HCID 86749217, compound

HRID 1449696Notes

Reaction equation

HRID 1449696 reaction equation
[CH2:1]([Sn:19](Cl)([CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][CH2:44][CH2:45][CH2:46][CH2:47][CH2:48][CH2:49][CH2:50][CH2:51][CH2:52][CH2:53][CH2:54][CH3:55])[CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH3:37])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18].[N-:57]=[N+:58]=[N-:59].[Na+]>C1(C)C=CC=CC=1>[CH2:1]([Sn:19]([N:57]=[N+:58]=[N-:59])([CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][CH2:44][CH2:45][CH2:46][CH2:47][CH2:48][CH2:49][CH2:50][CH2:51][CH2:52][CH2:53][CH2:54][CH3:55])[CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH3:37])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18]

Participants

4

Reactant 2

HCID 33557Sodium AzideHCID 301295Stannane, chlorotrioctadecyl-

Product 1

HCID 86749217HCID 86749217, compoundYield 68.5%

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent2×

Conditions

Temperature
120 °C

Procedure

A mixture of 20.0 g of trioctadecyltin chloride, 3.0 g of sodium azide and 40 ml of toluene was stirred at 120° C. for 6 hours. After cooling, 100 ml of toluene was added to the reaction mixture. The toluene layer was washed with water, dried over magnesium sulfate and concentrated under reduced pressure to give 13.8 g of trioctadecyltin azide.

Workup

  1. temperatureAfter cooling
  2. washThe toluene layer was washed with water
  3. dry with materialdried over magnesium sulfate
  4. concentrationconcentrated under reduced pressure

Sources & evidence

ORD record
ord-50268ca960ab49cca717e03226b36b45
Source dataset
uspto-grants-1997_02
Patent number
US05599943

Reaction notes

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