(2R,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexanal → HCID 53844535, compound

HRID 1450137Notes

Reaction equation

HRID 1450137 reaction equation
O=C[C@@H]([C@H]([C@@H]([C@@H](CO)O)O)O)O.[CH2:13]([NH:17][CH2:18][C@@H:19]([C@H:21]([C@@H:23]([C@@H:25]([CH2:27][OH:28])[OH:26])[OH:24])[OH:22])[OH:20])[CH2:14][CH2:15][CH3:16]>>[CH2:13]([NH:17][CH2:18][C@@H:19]1[O:20][C@:25]([OH:26])([CH2:27][OH:28])[C@@H:23]([OH:24])[C@@H:21]1[OH:22])[CH2:14][CH2:15][CH3:16]

Participants

3

Reactant 2

HCID 107526(2R,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexanalHCID 13424553HCID 13424553, compound

Product 1

HCID 53844535HCID 53844535, compound

Procedure

The process of claim 1 in which D-glucose is aminated to N-n-butyl glucamine which in turn is oxidized to produce 6-n-butylamino-6-deoxy-α-L-sorbofuranose which is reduced to produce N-n-butyl-1-deoxynojirimycin.

Sources & evidence

ORD record
ord-6849d9fedd0d4a64bc461bd6ee18f028
Source dataset
uspto-grants-1997_02
Patent number
US05602013

Reaction notes

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