Sodium Azide → HCID 178422996, compound

HRID 1450569Notes

Reaction equation

HRID 1450569 reaction equation
[CH:1]1([C:4]2[N:8]([CH2:9][C:10]3[CH:15]=[CH:14][C:13]([C:16]4[CH:21]=[CH:20][CH:19]=[CH:18][C:17]=4[C:22]#[N:23])=[CH:12][CH:11]=3)[C:7]3[CH:24]=[C:25]([C:29]4[N:33]([CH3:34])[C:32]5[CH:35]=[CH:36][CH:37]=[CH:38][C:31]=5[N:30]=4)[CH:26]=[C:27]([CH3:28])[C:6]=3[N:5]=2)[CH2:3][CH2:2]1.[N-:39]=[N+:40]=[N-:41].[Na+]>CN(C)C=O>[CH:1]1([C:4]2[N:8]([CH2:9][C:10]3[CH:11]=[CH:12][C:13]([C:16]4[CH:21]=[CH:20][CH:19]=[CH:18][C:17]=4[C:22]4[NH:41][N:40]=[N:39][N:23]=4)=[CH:14][CH:15]=3)[C:7]3[CH:24]=[C:25]([C:29]4[N:33]([CH3:34])[C:32]5[CH:35]=[CH:36][CH:37]=[CH:38][C:31]=5[N:30]=4)[CH:26]=[C:27]([CH3:28])[C:6]=3[N:5]=2)[CH2:3][CH2:2]1

Participants

4

Reactant 2

HCID 33557Sodium AzideHCID 19964544HCID 19964544, compound

Product 1

HCID 178422996HCID 178422996, compound

Reagents, catalysts & solvents 1

HCID 6228DimethylformamideSolvent

Procedure

Prepared analogously to Example 10 from 4'-[(2-cyclopropyl-4-methyl-6-(1-methylbenzimidazol-2-yl)-benzimidazol-1-yl)-methyl]-2-cyano-biphenyl and sodium azide in dimethylformamide.

Sources & evidence

ORD record
ord-5742fab5bc5b4ef08f94cd3c85eba535
Source dataset
uspto-grants-1997_02
Patent number
US05602127

Reaction notes

Loading…