Water → Gluconic Acid

HRID 1451666Notes

Reaction equation

HRID 1451666 reaction equation
[O:1]=[CH:2][C@@H:3]([C@H:5]([C@@H:7]([C@@H:9]([CH2:11][OH:12])[OH:10])[OH:8])[OH:6])[OH:4].[OH2:13]>>[O:1]=[C:2]([OH:13])[C@@H:3]([C@H:5]([C@@H:7]([C@@H:9]([CH2:11][OH:12])[OH:10])[OH:8])[OH:6])[OH:4]

Participants

3

Reactant 2

HCID 962WaterHCID 107526(2R,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexanal

Product 1

HCID 10690Gluconic Acid

Procedure

In 400 g of water was dissolved 100 g of glucose followed by addition of 0.5 g of the same enzyme preparation as used in Example 2. The reaction was then conducted aerobically at 23° C. for 90 minutes to provide a gluconic acid-containing glucose syrup. The result of assay of gluconic acid in this glucose syrup by high performance liquid chromatography is shown in Table 12.

Workup

  1. additionfollowed by addition of 0.5 g of the same enzyme preparation

Sources & evidence

ORD record
ord-5b534357de3c4f4ead6064791461f2ba
Source dataset
uspto-grants-1997_02
Patent number
US05605697

Reaction notes

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