Methacryloyl chloride → N-allyl-N-(2-methacryloyloxyethyl)-4-(4'-nitrophenylazo) benzenamine

HRID 1451675Notes

Reaction equation

HRID 1451675 reaction equation
[CH2:1]([N:4]([CH2:22][CH2:23][OH:24])[C:5]1[CH:10]=[CH:9][C:8]([N:11]=[N:12][C:13]2[CH:18]=[CH:17][C:16]([N+:19]([O-:21])=[O:20])=[CH:15][CH:14]=2)=[CH:7][CH:6]=1)[CH:2]=[CH2:3].[C:25](Cl)(=[O:29])[C:26]([CH3:28])=[CH2:27]>>[CH2:1]([N:4]([CH2:22][CH2:23][O:24][C:25](=[O:29])[C:26]([CH3:28])=[CH2:27])[C:5]1[CH:6]=[CH:7][C:8]([N:11]=[N:12][C:13]2[CH:18]=[CH:17][C:16]([N+:19]([O-:21])=[O:20])=[CH:15][CH:14]=2)=[CH:9][CH:10]=1)[CH:2]=[CH2:3]

Participants

3

Reactant 2

HCID 13528Methacryloyl chlorideHCID 19702708N-allyl-N-(2-hydroxyethyl)-4-(4'-nitrophenylazo)benzenamine

Product 1

HCID 19702674N-allyl-N-(2-methacryloyloxyethyl)-4-(4'-nitrophenylazo) benzenamine

Procedure

N-allyl-N-(2-hydroxyethyl)-4-(4'-nitrophenylazo)benzenamine (3.26 g, 0.01 mol) is treated with methacryloyl chloride, as discussed in Example 8, to provide N-allyl-N-(2-methacryloyloxyethyl)-4-(4'-nitrophenylazo) benzenamine.

Sources & evidence

ORD record
ord-18d33daa48524527baa553018d22f664
Source dataset
uspto-grants-1997_02
Patent number
US05605726

Reaction notes

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