tert-Butyl mercaptan → t-Butyl disulfide

HRID 1452010Notes

Reaction equation

HRID 1452010 reaction equation
[C:1]([SH:5])([CH3:4])([CH3:3])[CH3:2]>C(#N)C>[C:1]([S:5][S:5][C:1]([CH3:4])([CH3:3])[CH3:2])([CH3:4])([CH3:3])[CH3:2]

Participants

3

Reactant 1

HCID 6387tert-Butyl mercaptan

Product 1

HCID 66060t-Butyl disulfide

Reagents, catalysts & solvents 1

HCID 6342AcetonitrileSolvent2×

Procedure

A 150 μg portion of LL-E33288γ1 -I in 1 ml of acetonitrile was treated with 50 μl of a 1μ mole/ml solution of t-butyl mercaptan in acetonitrile. After 21/4 hours, the reaction was complete, giving the t-butyl disulfide of LL-E33288γ1 -I.

Workup

  1. custom4 hours

Sources & evidence

ORD record
ord-f59513445c4b4931ab766c5d55c2f71d
Source dataset
uspto-grants-1997_02
Patent number
US05606040

Reaction notes

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