HRID1457535

反应详情

EQUATION

反应方程式

REACTANTS

反应物

反应SMILES：CC(=O)OC[C@H]1O[C@@H](N=[N+]=[N-])[C@H](OC(C)=O)[C@@H](OC(C)=O)[C@@H]1OC(C)=O

HCID2725013

未命名化合物

PRODUCTS

产物

反应SMILES：[N-]=[N+]=N[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O

HCID11074507

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID887

Methanol

CH4O

CONDITIONS

反应条件

温度: 0 °C

PROCEDURE

实验过程

To a solution of 2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl azide (3, 5.6 g) in methanol (50 ml) 1M methanolic sodium methoxide (0.5 ml) was added and the solution was stirred overnight at 0° C., then it was neutralized with AG 50W-X8 (H+) ion-exchange resin. The resin was filtered off, the filtrate was evaporated and dried in vacuo to give the known β-D-glucopyranosyl azide (4).

WORKUP

后处理

filtrationThe resin was filtered off
customthe filtrate was evaporated
customdried in vacuo