HCID 2725013, compound → HCID 11074507, compound

HRID 1457535Notes

Reaction equation

HRID 1457535 reaction equation
C([O:4][C@@H:5]1[C@@H:10]([O:11]C(=O)C)[C@H:9]([O:15]C(=O)C)[C@@H:8]([CH2:19][O:20]C(=O)C)[O:7][C@H:6]1[N:24]=[N+:25]=[N-:26])(=O)C>CO>[C@@H:6]1([N:24]=[N+:25]=[N-:26])[O:7][C@H:8]([CH2:19][OH:20])[C@@H:9]([OH:15])[C@H:10]([OH:11])[C@H:5]1[OH:4]

Participants

3

Reactant 1

HCID 2725013HCID 2725013, compound

Product 1

HCID 11074507HCID 11074507, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Conditions

Temperature
0 °C

Procedure

To a solution of 2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl azide (3, 5.6 g) in methanol (50 ml) 1M methanolic sodium methoxide (0.5 ml) was added and the solution was stirred overnight at 0° C., then it was neutralized with AG 50W-X8 (H+) ion-exchange resin. The resin was filtered off, the filtrate was evaporated and dried in vacuo to give the known β-D-glucopyranosyl azide (4).

Workup

  1. filtrationThe resin was filtered off
  2. customthe filtrate was evaporated
  3. customdried in vacuo

Sources & evidence

ORD record
ord-3585bd82d46f4612a1b69b4cdc7f503b
Source dataset
uspto-grants-1998_12
Patent number
US05849709

Reaction notes

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