AC1MBFZI → HCID 11273668, compound

HRID 1457537Notes

Reaction equation

HRID 1457537 reaction equation
[N:1]([C@@H:4]1[O:41][C@H:40]([CH2:42][O:43][C:44](=[O:46])[CH3:45])[C@@H:15]([O:16][C@@H:17]2[O:34][C@H:33]([CH2:35][O:36][C:37](=[O:39])[CH3:38])[C@@H:28]([O:29][C:30](=[O:32])[CH3:31])[C@H:23]([O:24][C:25](=[O:27])[CH3:26])[C@H:18]2[O:19][C:20](=[O:22])[CH3:21])[C@H:10]([O:11][C:12](=[O:14])[CH3:13])[C@H:5]1[O:6][C:7](=[O:9])[CH3:8])=[N+]=[N-]>C(OCC)(=O)C.[Pd]>[NH2:1][C@@H:4]1[O:41][C@H:40]([CH2:42][O:43][C:44](=[O:46])[CH3:45])[C@@H:15]([O:16][C@@H:17]2[O:34][C@H:33]([CH2:35][O:36][C:37](=[O:39])[CH3:38])[C@@H:28]([O:29][C:30](=[O:32])[CH3:31])[C@H:23]([O:24][C:25](=[O:27])[CH3:26])[C@H:18]2[O:19][C:20](=[O:22])[CH3:21])[C@H:10]([O:11][C:12](=[O:14])[CH3:13])[C@H:5]1[O:6][C:7](=[O:9])[CH3:8]

Participants

4

Reactant 1

HCID 2725016AC1MBFZI

Product 1

HCID 11273668HCID 11273668, compoundYield 100%

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 8857Ethyl AcetateSolvent

Procedure

A solution of 35 (0.67 g) in ethyl acetate (15 ml) was hydrogenated in the presence of Pd-C (0.3 g) at atmospheric pressure for one hour. Pd-C was filtered, and the solvent was evaporated to give 1-amino-1-deoxy-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-(1→4)-2,3,6-tri-O-acetyl-β-D-glucopyranose (36, 0.64 g, 100%).

Workup

  1. filtrationPd-C was filtered
  2. customthe solvent was evaporated

Sources & evidence

ORD record
ord-fddcb2dc5f5640689167cfb57a9325d0
Source dataset
uspto-grants-1998_12
Patent number
US05849709

Reaction notes

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