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HRID1458279

反应详情

EQUATION

反应方程式

HRID 1458279 的结构方程式

REACTANTS

反应物

2
结构：Cl
HCID313

Hydrochloric Acid

ClH

结构：CC(=O)Nc1ccc(S(F)(F)(F)(F)F)cc1[N+](=O)[O-]
HCID54537779

未命名化合物

PRODUCTS

生成物

1
结构：Nc1ccc(S(F)(F)(F)(F)F)cc1[N+](=O)[O-]
HCID45933650

未命名化合物

收率 98.7%

AUXILIARIES

试剂、催化剂与溶剂

1
结构：C1COCCO1
溶剂HCID31275

1,4-Dioxane

C4H8O2

PROCEDURE

实验过程

4-Acetamido-3-nitrophenylsulphur pentafluoride (29.0 g) was heated at reflux with hydrochloric acid (6N) and dioxan for 40 minutes and concentrated to low volume, basified with sodium carbonate solution and extracted (ether). The extract was washed (water), dried (magnesium sulphate) and evaporated to give 4-amino-3-nitrophenylsulphur pentafluoride (24.7 g), m.p.132°-1350° C.

WORKUP

后处理

  1. concentrationconcentrated to low volume
  2. extractionextracted (ether)
  3. washThe extract was washed (water)
  4. dry with materialdried (magnesium sulphate)
  5. customevaporated