関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Water | HCID 962 | — |
| 反応物 | Acetic Anhydride | HCID 7918 | — |
| 反応物 | 4-Aminophenylsulphur pentafluoride | HCID 2779190 | — |
| 溶媒 | Acetic Acid | HCID 176 | — |
| 生成物 | N-[4-(Pentafluorosulfanyl)phenyl]acetamide | HCID 21576972 | — |
反応手順
Acetic anhydride was added during 5 minutes to a stirred solution of 4-aminophenylsulphur pentafluoride (30.2 g) in acetic acid at 40° C. and then heated at 65° C. for 0.5 hour. The cooled mixture was added to water, stirred for 1 hour and filtered. The solid was washed with water, sodium bicarbonate solution and water, dried and purified by stirring with hexane to give 4-acetamidophenylsulphur pentafluoride (27.0 g), m.p.131°-132° C.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US05849928 |
|---|
| 出典データセット | uspto-grants-1998_12 |
|---|
| ORD ID | ord-229c361bfc174557bb83b35e44524864 |
|---|
| 出典メモ | uspto-grants-1998_12 |
|---|
