HRID1458316

反应详情

EQUATION

反应方程式

REACTANTS

反应物

$结构：CC(=O)OC/C(=C(\CO)c1ccccc1)c1ccc(S(C)(=O)=O)cc1$

HCID58787789

未命名化合物

PRODUCTS

生成物

$结构：CC(=O)OC/C(=C(\C=O)c1ccccc1)c1ccc(S(C)(=O)=O)cc1$

HCID86753445

未命名化合物

收率 74.8%

AUXILIARIES

试剂、催化剂与溶剂

催化剂HCID14801

Manganese oxide (Mn2O4)

MnO2

溶剂HCID6344

Dichloromethane

CH2Cl2

PROCEDURE

实验过程

A mixture of the acetate from Example 2 (215 mg) and MnO2 (1.2 g) in 30 mL of CH2Cl2 was stirred for 12 h at r.t., and then filtered through a pad of celite. The filtrate was concentrated to give 160 mg of the title compound as a yellow solid.

WORKUP

后处理

filtrationfiltered through a pad of celite
concentrationThe filtrate was concentrated