Triethylamine → Triethylmethylammonium methyl carbonate

HRID 1459877Notes

Reaction equation

HRID 1459877 reaction equation
[CH2:1]([N:3]([CH2:6][CH3:7])[CH2:4][CH3:5])[CH3:2].[C:8](=[O:13])([O:11]C)[O:9][CH3:10]>CO>[CH3:10][O:9][C:8](=[O:11])[O-:13].[CH3:8][N+:3]([CH2:6][CH3:7])([CH2:4][CH3:5])[CH2:1][CH3:2]

Participants

4

Reactant 2

HCID 8471TriethylamineHCID 12021Dimethyl Carbonate

Product 1

HCID 11019667Triethylmethylammonium methyl carbonate

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent2×

Procedure

Into an autoclave equipped with a stirrer were charged triethylamine (1 mole), dimethyl carbonate (1.5 mole) and methanol (2.0 mole), which were reacted at a reaction temperature of 110° C. for 12 hours to obtain a methanol solution of methyltriethylammoniummethyl carbonate. To the thus obtained solution was added octylic acid (1 mole) followed by removing carbon dioxide gas evolved and methanol to obtain methyltriethylammonium octylate (C-1).

Workup

  1. customInto an autoclave equipped with a stirrer
  2. customwere reacted at a reaction temperature of 110° C. for 12 hours

Sources & evidence

ORD record
ord-0714b6b7f3fe4b47927cb5cb7eca7493
Source dataset
uspto-grants-1998_12
Patent number
US05854360

Reaction notes

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