HuagongsheHuagongshe Chemistry Print Report · For research reference only
Dimethylformamide → Lithium bis((trifluoromethyl)sulfonyl)azanide
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Dimethylformamide | HCID 6228 | — |
| Reactant | Trifluoromethanesulfonyl chloride | HCID 79000 | — |
| Reactant | Lithium nitride | HCID 520242 | — |
| Solvent | 1,2-Dimethoxyethane | HCID 8071 | — |
| Product | Lithium bis((trifluoromethyl)sulfonyl)azanide | HCID 3816071 | — |
Reaction Steps
22 ml of trifluoromethanesulfonyl chloride were added to a suspension of 3.5 g of lithium nitride in 100 ml of a mixture of DMF and DME (50/50). The nitride dissolved in a few minutes with stirring at ambient temperature. The reaction took place according to the following reaction scheme:
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05072040 |
| Source dataset | uspto-grants-1991_12 |
| ORD ID | ord-3cbedff97cb3469ea86b63b8f07f1fc5 |
| Source note | uspto-grants-1991_12 |