Dimethylformamide → Lithium bis((trifluoromethyl)sulfonyl)azanide

HRID 1460857Notes

Reaction equation

HRID 1460857 reaction equation
[F:1][C:2]([F:8])([F:7])[S:3](Cl)(=[O:5])=[O:4].[Li+:9].[Li+].[Li+].[NH2-:12].CN(C=O)C>COCCOC>[N-:12]([S:3]([C:2]([F:8])([F:7])[F:1])(=[O:5])=[O:4])[S:3]([C:2]([F:8])([F:7])[F:1])(=[O:5])=[O:4].[Li+:9]

Participants

5

Reactant 3

HCID 6228DimethylformamideHCID 79000Trifluoromethanesulfonyl chlorideHCID 520242LITHIUM NITRIDE

Product 1

HCID 3816071Lithium bis((trifluoromethyl)sulfonyl)azanide

Reagents, catalysts & solvents 1

HCID 80711,2-DimethoxyethaneSolvent

Procedure

22 ml of trifluoromethanesulfonyl chloride were added to a suspension of 3.5 g of lithium nitride in 100 ml of a mixture of DMF and DME (50/50). The nitride dissolved in a few minutes with stirring at ambient temperature. The reaction took place according to the following reaction scheme:

Workup

  1. customaccording to the following reaction scheme

Sources & evidence

ORD record
ord-3cbedff97cb3469ea86b63b8f07f1fc5
Source dataset
uspto-grants-1991_12
Patent number
US05072040

Reaction notes

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