HRID1461503

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：CO[C@@]12[C@H](COC(N)=O)C3=C(C(O)=C(C)C(=O)C3=O)N1C[C@@H]1N[C@@H]12

HCID11727393

未命名化合物

HCID178486252

未命名化合物

PRODUCTS

生成物

结构：COC1=C(C)C(=O)C2=C(C1=O)[C@@H](COC(N)=O)[C@@]1(OC)[C@H]3N[C@H]3CN21

HCID19972

Mitomycin A

C16H19N3O6

PROCEDURE

实验过程

7-Hydroxy-9a-methoxymitosane was alkylated with 3-methyl-I-p-tolyltriazene to give mitomycin A or with diazodiphenylmethane to give 7-(diphenylmethyl)oxy-9a-methoxymitosane (hereinafter 7-ODPM mitomycin).