Quinoline → HCID 13089648, compound

HRID 1462650Notes

Reaction equation

HRID 1462650 reaction equation
[CH3:1][C:2]([CH3:10])([CH2:7][CH2:8]Cl)[CH:3]=[C:4]([Cl:6])[Cl:5].N1C2C(=CC=CC=2)C=CC=1.C(=O)([O-])[O-].[K+].[K+]>>[Cl:5][C:4]([Cl:6])=[CH:3][C:2]([CH3:10])([CH3:1])[CH:7]=[CH2:8]

Participants

4

Reactant 3

HCID 7047Quinoline2×HCID 11430Potassium CarbonateHCID 155843271,1,5-Trichloro-3,3-dimethylpent-1-ene

Product 1

HCID 13089648HCID 13089648, compoundYield 73.3%

Procedure

201.5 g (1 mol) of 3,3-dimethyl-1,1,5-trichloro-1-pentene are slowly added dropwise into 1 l of quinoline, and 83 g potassium carbonate at 225° to 230° C., and distillate is simultaneously taken off via the head of a column. The temperature in the flask is raised to the boiling point of the quinoline, and a total of 126 g of distillate is isolated, the distillate again being fractionally distilled. 121 g (73% of theory) of 1,1-dichloro-3,3-dimethyl-1,4-pentadiene are obtained at a boiling point of 59°-53° C./20 mm Hg.

Workup

  1. customa total of 126 g of distillate is isolated
  2. distillationthe distillate again being fractionally distilled

Sources & evidence

ORD record
ord-d4f68bf967fe425c94f81a2de810871e
Source dataset
uspto-grants-1984_07
Patent number
US04460793

Reaction notes

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