Phenolate Sodium → HCID 53711277, compound

HRID 1462657Notes

Reaction equation

HRID 1462657 reaction equation
[Cl:1][C:2](Cl)=[CH:3][C:4]([CH3:7])([CH3:6])[CH3:5].[C:9]1([O-:15])[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1.[Na+]>CN(C)C=O>[Cl:1][CH:2]=[C:3]([O:15][C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1)[C:4]([CH3:7])([CH3:6])[CH3:5]

Participants

4

Reactant 2

HCID 4445035Phenolate SodiumHCID 112865761,1-dichloro-3,3-dimethyl-1-butene

Product 1

HCID 53711277HCID 53711277, compoundYield 98%

Reagents, catalysts & solvents 1

HCID 6228DimethylformamideSolvent

Procedure

16.5 g (0.108 mols) of 1,1-dichloro-3,3-dimethyl-1-butene are heated under reflux with 23.2 g (0.2 mol) of sodium phenolate in 100 ml of dimethylformamide, during the course of 12 hours. The customary working-up according to Example A1(a) yields, with distillation at a boiling point of 80° C./0.5 mm Hg, 22.3 g of 1-chloro-3,3-dimethyl-2-phenoxy-1-butene.

Sources & evidence

ORD record
ord-85deab2f33f946c5a9227753d15e8e5d
Source dataset
uspto-grants-1984_07
Patent number
US04460793

Reaction notes

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