HRID1462664

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID6371

Phosgene

CCl2O

结构：CCCCCCCCCCCCSCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO

HCID9961026

未命名化合物

结构：CCCCC(CC)CCC(CC(C)C)OS(=O)(=O)[O-].[Na+]

HCID23665772

7-Ethyl-2-methyl-4-undecanolsulfate, sodium salt

C14H29NaO4S

PRODUCTS

生成物

结构：CCCCCCCCCCCCSCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOC(=O)Cl

HCID131713586

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID8471

Triethylamine

C6H15N

PROCEDURE

实验过程

For example, C12H25S(CH2CH2O)10H, such as Tergitol 12-M10, can be reacted with phosgene in the presence of triethyl amine to yield the corresponding acid chloride, C12H25S(CH2CH2O)10COCl, which in turn, is reacted with a fluoroaliphatic alcohol such as (CF3)2CFO--CF2CF2 --CH2CH2CONH(CH2)3OH, disclosed in U.S. Pat. No. 3,697,564, in the presence of triethylamine in diethyl ether to yield a product of the formula (CF3)2CFO--CF2CF2CH2CH2CONH(CH2)3OCO(OCH2CH2)10S--C12H25.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-b0e8f681e4f747a8ad3dc6d8a6705aac
来源数据集: uspto-grants-1984_07
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04460791
来源说明: uspto-grants-1984_07

反应 SMILES

[CH2:1]([S:13][CH2:14][CH2:15][O:16][CH2:17][CH2:18][O:19][CH2:20][CH2:21][O:22][CH2:23][CH2:24][O:25][CH2:26][CH2:27][O:28][CH2:29][CH2:30][O:31][CH2:32][CH2:33][O:34][CH2:35][CH2:36][O:37][CH2:38][CH2:39][O:40][CH2:41][CH2:42][OH:43])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12].CCCCC(CCC(OS([O-])(=O)=O)CC(C)C)CC.[Na+].[C:64](Cl)([Cl:66])=[O:65]>C(N(CC)CC)C>[CH2:1]([S:13][CH2:14][CH2:15][O:16][CH2:17][CH2:18][O:19][CH2:20][CH2:21][O:22][CH2:23][CH2:24][O:25][CH2:26][CH2:27][O:28][CH2:29][CH2:30][O:31][CH2:32][CH2:33][O:34][CH2:35][CH2:36][O:37][CH2:38][CH2:39][O:40][CH2:41][CH2:42][O:43][C:64]([Cl:66])=[O:65])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12]