HRID1462932

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID14798

Sodium Hydroxide

HNaO

结构：CC1(C)CC(NCCCCCCNC2CC(C)(C)NC(C)(C)C2)CC(C)(C)N1

HCID93419

1,6-Bis(2,2,6,6-tetramethyl-4-piperidylamino)hexane

C24H50N4

HCID20452243

未命名化合物

PRODUCTS

生成物

结构：C=CCOc1nc(NC(C)(C)CC(C)(C)C)nc(N(CCCCCCN(c2nc(NC(C)(C)CC(C)(C)C)nc(OCC=C)n2)C2CC(C)(C)NC(C)(C)C2)C2CC(C)(C)NC(C)(C)C2)n1

HCID20452227

未命名化合物

收率 68.3%

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID7237

o-Xylene

C8H10

PROCEDURE

实验过程

A stirred mixture of 4,4'(hexamethylenediimino)bis(2,2,6,6-tetramethylpiperidine) (10.0 grams; 0.025 mole), 2-allyloxy-4-chloro-6-t-octylamino-1,3,5-triazine (15.1 grams; 0.05 mole), and powdered sodium hydroxide (2.0 grams; 0.05 mole) in xylene (150 mls) is heated at reflux for 24 hours while removing by-product water by means of a trap. The reaction mixture is filtered while hot to remove insolubles. Upon cooling the filtrate, a white crystalline solid precipitates. The solid is recovered by filtration and dried to obtain 15.7 grams of the desired product, mp 210°-212° C.

WORKUP

后处理

temperatureis heated
temperatureat reflux for 24 hours
customwhile removing by-product water by means of a trap
filtrationThe reaction mixture is filtered while hot
customto remove insolubles
temperatureUpon cooling the filtrate
customa white crystalline solid precipitates
filtrationThe solid is recovered by filtration
customdried

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-e7ee6dd4cc43496bb245f8093b2477e2
来源数据集: uspto-grants-1984_07
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04461861
来源说明: uspto-grants-1984_07

反应 SMILES

[NH:1]([CH:19]1[CH2:24][C:23]([CH3:26])([CH3:25])[NH:22][C:21]([CH3:28])([CH3:27])[CH2:20]1)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][NH:8][CH:9]1[CH2:14][C:13]([CH3:16])([CH3:15])[NH:12][C:11]([CH3:18])([CH3:17])[CH2:10]1.[CH2:29]([O:32][C:33]1[N:38]=[C:37](Cl)[N:36]=[C:35]([NH:40][C:41]([CH2:44][C:45]([CH3:48])([CH3:47])[CH3:46])([CH3:43])[CH3:42])[N:34]=1)[CH:30]=[CH2:31].[OH-:49].[Na+]>C1(C)C(C)=CC=CC=1>[CH3:25][C:23]1([CH3:26])[CH2:24][CH:19]([N:1]([C:37]2[N:38]=[C:33]([O:49][CH2:31][CH:30]=[CH2:29])[N:34]=[C:35]([NH:40][C:41]([CH2:44][C:45]([CH3:46])([CH3:48])[CH3:47])([CH3:43])[CH3:42])[N:36]=2)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][N:8]([C:37]2[N:38]=[C:33]([O:32][CH2:29][CH:30]=[CH2:31])[N:34]=[C:35]([NH:40][C:41]([CH2:44][C:45]([CH3:48])([CH3:47])[CH3:46])([CH3:43])[CH3:42])[N:36]=2)[CH:9]2[CH2:14][C:13]([CH3:16])([CH3:15])[NH:12][C:11]([CH3:17])([CH3:18])[CH2:10]2)[CH2:20][C:21]([CH3:28])([CH3:27])[NH:22]1