Ammonia → HCID 19088340, compound

HRID 1463768Notes

Reaction equation

HRID 1463768 reaction equation
[Na].C([S:9][C:10]1[CH:47]=[CH:46][CH:45]=[CH:44][C:11]=1[CH2:12][NH:13][CH2:14][C:15]([CH3:43])([CH2:33][C:34]1[CH:39]=[CH:38][C:37]([N+:40]([O-:42])=[O:41])=[CH:36][CH:35]=1)[CH2:16][NH:17][CH2:18][C:19]1[CH:24]=[CH:23][CH:22]=[CH:21][C:20]=1[S:25]CC1C=CC=CC=1)C1C=CC=CC=1.N>>[SH:9][C:10]1[CH:47]=[CH:46][CH:45]=[CH:44][C:11]=1[CH2:12][NH:13][CH2:14][C:15]([CH3:43])([CH2:33][C:34]1[CH:35]=[CH:36][C:37]([N+:40]([O-:42])=[O:41])=[CH:38][CH:39]=1)[CH2:16][NH:17][CH2:18][C:19]1[CH:24]=[CH:23][CH:22]=[CH:21][C:20]=1[SH:25]

Participants

4

Reactant 3

HCID 222AmmoniaHCID 5360545SodiumHCID 19088323HCID 19088323, compound

Product 1

HCID 19088340HCID 19088340, compound

Procedure

Sodium was added to a solution of 1.24 g [70] (2.0 mmol) in 30 ml liquid ammonia until the colour became permanently blue. After thirty minutes the excess sodium was destroyed by adding ammonium chloride. After the ammonia evaporated, the residue was dissolved in water and extracted with chloroform. After drying and removal of the solvent, a white residue was left.

Workup

  1. customAfter thirty minutes the excess sodium was destroyed
  2. additionby adding ammonium chloride
  3. customAfter the ammonia evaporated
  4. dissolutionthe residue was dissolved in water
  5. extractionextracted with chloroform
  6. customAfter drying
  7. customremoval of the solvent
  8. waita white residue was left

Sources & evidence

ORD record
ord-03ba18549f864f1fae2837b6cd593d78
Source dataset
uspto-grants-1994_04
Patent number
US05302370

Reaction notes

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