Dimethylcyanamide → HCID 178503142, compound

HRID 1464067Notes

Reaction equation

HRID 1464067 reaction equation
Cl.[NH2:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][C:4]=1[C:9]1[CH:14]=[CH:13][CH:12]=[C:11]([S:15][CH3:16])[CH:10]=1.[CH3:17][N:18]([CH3:21])[C:19]#[N:20]>C1C(O)=CC=CC=1C>[CH3:17][N:18]([CH3:21])[C:19]([NH:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][C:4]=1[C:9]1[CH:14]=[CH:13][CH:12]=[C:11]([S:15][CH3:16])[CH:10]=1)=[NH:20]

Participants

4

Reactant 2

HCID 15112DimethylcyanamideHCID 190892992-Amino-3'-methylthiobiphenyl hydrochloride

Product 1

HCID 178503142HCID 178503142, compound

Reagents, catalysts & solvents 1

HCID 342M-CresolSolvent

Procedure

A mixture of 2-amino-3'-methylthiobiphenyl hydrochloride (3.3 g), N,N-dimethylcyanamide (1.55 ml) and m-cresol (10 ml) was heated at 90°-95° C. for 14 hours to give N,N-dimethyl-N'-(3'-methylthio-2-biphenylyl)guanidine (m.p. 94°-95° C.) which was recrystallised from hexane.

Workup

  1. temperaturewas heated at 90°-95° C. for 14 hours

Sources & evidence

ORD record
ord-6abb07d2ff204bb5901b5d52806b6fa5
Source dataset
uspto-grants-1994_04
Patent number
US05302720

Reaction notes

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