HuagongsheHuagongshe Chemistry Print Report · For research reference only
2-Aminobiphenyl → 1-Isothiocyanato-2-phenylbenzene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2-Aminobiphenyl | HCID 7015 | — |
| Reactant | Thiophosgene | HCID 10040 | — |
| Solvent | Water | HCID 962 | — |
| Solvent | 1,4-Dioxane | HCID 31275 | — |
| Product | 1-Isothiocyanato-2-phenylbenzene | HCID 519659 | — |
Reaction Steps
Reaction of 2-aminobiphenyl (10 g) with thiophosgene (10.2 g) in a mixture of dioxane (15 ml) and water (50 ml) at 0°-5° C. for 30 minutes and at ambient temperature for 2 hours with stirring gave 2-biphenylylisothiocyanate as a yellow oil.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05302720 |
| Source dataset | uspto-grants-1994_04 |
| ORD ID | ord-d753fb2fe9f74e71b25a946ebc5261d1 |
| Source note | uspto-grants-1994_04 |