HuagongsheHuagongshe Chemistry Print Report · For research reference only
Thiophosgene → 4-Methylthio-2-biphenylylisothiocyanate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Thiophosgene | HCID 10040 | — |
| Reactant | 2-Amino-4-methylthiobiphenyl | HCID 19089196 | — |
| Solvent | Water | HCID 962 | — |
| Solvent | 1,4-Dioxane | HCID 31275 | — |
| Product | 4-Methylthio-2-biphenylylisothiocyanate | HCID 19089282 | — |
Reaction Steps
Reaction of 2-amino-4-methylthiobiphenyl (10.8 g) with thiophosgene (4.6 ml) in a mixture of dioxan (10 ml) and water (200 ml) at 10° C. and then at ambient temperature for 15 hours yielded 4-methylthio-2-biphenylylisothiocyanate as a yellow oil.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05302720 |
| Source dataset | uspto-grants-1994_04 |
| ORD ID | ord-1b0c6b8c961540109926ec7f5150e84c |
| Source note | uspto-grants-1994_04 |